You're passing the array instead of creating it inside the function, which you seem to want to do given the line r=np.array([a,b,c]).
Assuming x is the same as ct, try P2 = FourVector(99.9,1,2,3). Otherwise, make sure you decide on whether you want to call your parameter ct or x. You pass in ct but you use x inside your function.
You also have a name issue with your class, which you declare asFV but you try to use as FourVector. Try to be a bit more careful with your names!
Given some decisions about it, your code should look like this:
import numpy as np
class FourVector:
def __init__(self,ct=0,a=0,b=0,c=0):
r=np.array([a,b,c])
self.t=ct
self.s=r
which you can then call as
P2 = FourVector(99.9,1,2,3)
Also note that since you assign r and then s=r, you can just do self.s=np.array([a,b,c]) directly, unless you have some reason to keep r around separately.