collectionToArray (col)
Notice that whitespace between the function's name and its argument list? That's the VBE telling you this:
I'll take that argument, evaluate it as a value, then pass it ByVal to that procedure you're calling, even if the signature for that procedure says ByRef, explicitly or not.
This "extraneous parentheses" habit is inevitably going to make you bump into weird "Object Required" runtime errors at one point or another: lose it.
The Function is overdoing it IMO: a Variant can perfectly well wrap an array, so I'd change its signature to return a Variant instead of a Variant().
Integer being a 16-bit signed integer type (i.e. short in some other languages), it's probably a better idea to use a Long instead (32-bit signed integer, i.e. int in some other languages) - that way you'll avoid running into "Overflow" issues when you need to deal with more than 32,767 values (especially common if a worksheet is involved).
Public col As New Collection
This makes col an auto-instantiated object variable, and it has potentially surprising side-effects. Consider this code:
Dim c As New Collection
c.Add 42
Set c = Nothing
c.Add 42
Debug.Print c.Count
What do you expect this code to do? If you thought "error 91, because the object reference is Nothing", you've been bitten by auto-instantiation. Best avoid it, and keep declaration and assignments as separate instructions.
Other than that, CLR's answer has your solution: a Function should return a value, that the calling code should consume.
result = MyFunction(args)
You'll notice the VBE clearing any whitespace you might be tempted to add between MyFunction and (args) here: that's the VBE telling you this:
I'll take that argument, pass it to MyFunction, and assign the function's return value to result.